No, account switching is currently only available to business accounts using free email domains, e.g., Gmail or Yahoo. For example, account switching is available for "yourcompany@gmail.com" but not "you@yourcompany.com".
Switch between your Amazon and Amazon Business accounts, without logging out.
Say goodbye to time spent logging in and out between your personal Amazon account and your Amazon Business account. Keep your personal and business account activity separate while using the same login credentials, security settings, and mobile number across accounts. Maintain a safe separation of payment and order information between your personal and business accounts, while seamlessly navigating between the two with a simple toggle. Account switching is currently only available for business accounts using free email domains.
Use the drop-down menu to switch between your business and personal accounts, or to add a new account.
Establish purchasing guidelines for your account and enable your team members to make purchases independently and securely. No need to share your login credentials, just add your colleagues as users to your business account.